Unusual Magnetic Properties of a Two-coordinate Heteroleptic Linear Cobalt(II) Complex

Chengbao Ni; Troy A. Stich; Gary J. Long; Philip P. Power

doi:10.1039/c001483d

Unusual Magnetic Properties of a Two-coordinate Heteroleptic Linear Cobalt(II) Complex

Chengbao Ni
, Troy A. Stich
, Gary J. Long
, Philip P. Power

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The synthesis and characterization of two-coordinate cobalt(ii) complexes CoAr′2 (1) and Ar′CoN(SiMe3)2 (2) (Ar′ = C6H3-2,6-(C6H3-2,6- iPr2)2) are reported. The magnetic data for 2 show that it has an unexpectedly high μeff of 5.65 μB whereas the bent complex 1 has a significantly lower moment. © 2010 The Royal Society of Chemistry.

Original language	American English
Journal	Chemical Communications
DOIs	https://doi.org/10.1039/c001483d
State	Published - Jan 1 2010

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Chemistry

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title = "Unusual Magnetic Properties of a Two-coordinate Heteroleptic Linear Cobalt(II) Complex",

abstract = " The synthesis and characterization of two-coordinate cobalt(ii) complexes CoAr′2 (1) and Ar′CoN(SiMe3)2 (2) (Ar′ = C6H3-2,6-(C6H3-2,6- iPr2)2) are reported. The magnetic data for 2 show that it has an unexpectedly high μeff of 5.65 μB whereas the bent complex 1 has a significantly lower moment. {\textcopyright} 2010 The Royal Society of Chemistry.",

author = "Chengbao Ni and Stich, \{Troy A.\} and Long, \{Gary J.\} and Power, \{Philip P.\}",

year = "2010",

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doi = "10.1039/c001483d",

language = "American English",

journal = "Chemical Communications",

issn = "1364-548X",

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T1 - Unusual Magnetic Properties of a Two-coordinate Heteroleptic Linear Cobalt(II) Complex

AU - Ni, Chengbao

AU - Stich, Troy A.

AU - Long, Gary J.

AU - Power, Philip P.

PY - 2010/1/1

Y1 - 2010/1/1

N2 - The synthesis and characterization of two-coordinate cobalt(ii) complexes CoAr′2 (1) and Ar′CoN(SiMe3)2 (2) (Ar′ = C6H3-2,6-(C6H3-2,6- iPr2)2) are reported. The magnetic data for 2 show that it has an unexpectedly high μeff of 5.65 μB whereas the bent complex 1 has a significantly lower moment. © 2010 The Royal Society of Chemistry.

AB - The synthesis and characterization of two-coordinate cobalt(ii) complexes CoAr′2 (1) and Ar′CoN(SiMe3)2 (2) (Ar′ = C6H3-2,6-(C6H3-2,6- iPr2)2) are reported. The magnetic data for 2 show that it has an unexpectedly high μeff of 5.65 μB whereas the bent complex 1 has a significantly lower moment. © 2010 The Royal Society of Chemistry.

UR - https://scholarsmine.mst.edu/chem_facwork/970

UR - https://doi.org/10.1039/c001483d

U2 - 10.1039/c001483d

DO - 10.1039/c001483d

M3 - Article

C2 - 20490404

SN - 1364-548X

JO - Chemical Communications

JF - Chemical Communications

ER -

Unusual Magnetic Properties of a Two-coordinate Heteroleptic Linear Cobalt(II) Complex

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