The ¹¹⁵Sn, ¹¹⁷Sn and ¹¹⁹Sn Nuclear Spin-rotation Constants in Stannous Monoxide, SnO, and a New Multi-isotopomer Analysis

Christopher T. Dewberry; Kerry C. Etchinson; Garry S. Grubbs; Robert A. Powoski; Michal M. Serafin; Sean A. Peebles; Stephen A. Cooke

doi:10.1016/j.jms.2007.11.009

The ¹¹⁵Sn, ¹¹⁷Sn and ¹¹⁹Sn Nuclear Spin-rotation Constants in Stannous Monoxide, SnO, and a New Multi-isotopomer Analysis

Christopher T. Dewberry
, Kerry C. Etchinson
, Garry S. Grubbs
, Robert A. Powoski
, Michal M. Serafin
, Sean A. Peebles
, Stephen A. Cooke

Missouri University of Science and Technology

Research output: Contribution to journal › Article › peer-review

Abstract

A Fourier transform microwave spectrometer has been used to make high resolution measurements on the J =1-0 rotational transition for 11 isotopomers of SnO. For the most abundant isotopomer the transition was observed in the v 0,1,2, and 3 states. Magnetic hyperfine structure was observed in the transitions for ¹¹⁵ Sn ¹⁶ O, ¹¹⁷ Sn ¹⁶ O and ¹¹⁹ Sn ¹⁶ O. the nuclear spin-rotation constant C _I (Sn) has been determined for these isotopomers for the first time and these constants have been related to nmr shielding parameters. a multi-isotopomer analysis, including data from the ¹²⁰ Sn ¹⁷ O and ¹²⁰ Sn ¹⁸ O isotopomers, has been performed on the data. Born-Oppenheimer breakdown parameters were required in the fit and these parameters have been compared to those for the other Sn-chalcogenides.

Original language	American English
Journal	Journal of Molecular Spectroscopy
Volume	248
DOIs	https://doi.org/10.1016/j.jms.2007.11.009
State	Published - Jan 1 2008

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Chemistry

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https://doi.org/10.1016/j.jms.2007.11.009

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@article{987e0bedbbd74726a1226aa18590705e,

title = "The ¹¹⁵Sn, ¹¹⁷Sn and ¹¹⁹Sn Nuclear Spin-rotation Constants in Stannous Monoxide, SnO, and a New Multi-isotopomer Analysis",

abstract = " A Fourier transform microwave spectrometer has been used to make high resolution measurements on the J =1-0 rotational transition for 11 isotopomers of SnO. For the most abundant isotopomer the transition was observed in the v 0,1,2, and 3 states. Magnetic hyperfine structure was observed in the transitions for 115 Sn 16 O, 117 Sn 16 O and 119 Sn 16 O. the nuclear spin-rotation constant C I (Sn) has been determined for these isotopomers for the first time and these constants have been related to nmr shielding parameters. a multi-isotopomer analysis, including data from the 120 Sn 17 O and 120 Sn 18 O isotopomers, has been performed on the data. Born-Oppenheimer breakdown parameters were required in the fit and these parameters have been compared to those for the other Sn-chalcogenides.",

author = "Dewberry, \{Christopher T.\} and Etchinson, \{Kerry C.\} and Grubbs, \{Garry S.\} and Powoski, \{Robert A.\} and Serafin, \{Michal M.\} and Peebles, \{Sean A.\} and Cooke, \{Stephen A.\}",

year = "2008",

month = jan,

day = "1",

doi = "10.1016/j.jms.2007.11.009",

language = "American English",

volume = "248",

journal = "Journal of Molecular Spectroscopy",

issn = "1096-083X",

}

TY - JOUR

T1 - The ¹¹⁵Sn, ¹¹⁷Sn and ¹¹⁹Sn Nuclear Spin-rotation Constants in Stannous Monoxide, SnO, and a New Multi-isotopomer Analysis

AU - Dewberry, Christopher T.

AU - Etchinson, Kerry C.

AU - Grubbs, Garry S.

AU - Powoski, Robert A.

AU - Serafin, Michal M.

AU - Peebles, Sean A.

AU - Cooke, Stephen A.

PY - 2008/1/1

Y1 - 2008/1/1

N2 - A Fourier transform microwave spectrometer has been used to make high resolution measurements on the J =1-0 rotational transition for 11 isotopomers of SnO. For the most abundant isotopomer the transition was observed in the v 0,1,2, and 3 states. Magnetic hyperfine structure was observed in the transitions for 115 Sn 16 O, 117 Sn 16 O and 119 Sn 16 O. the nuclear spin-rotation constant C I (Sn) has been determined for these isotopomers for the first time and these constants have been related to nmr shielding parameters. a multi-isotopomer analysis, including data from the 120 Sn 17 O and 120 Sn 18 O isotopomers, has been performed on the data. Born-Oppenheimer breakdown parameters were required in the fit and these parameters have been compared to those for the other Sn-chalcogenides.

AB - A Fourier transform microwave spectrometer has been used to make high resolution measurements on the J =1-0 rotational transition for 11 isotopomers of SnO. For the most abundant isotopomer the transition was observed in the v 0,1,2, and 3 states. Magnetic hyperfine structure was observed in the transitions for 115 Sn 16 O, 117 Sn 16 O and 119 Sn 16 O. the nuclear spin-rotation constant C I (Sn) has been determined for these isotopomers for the first time and these constants have been related to nmr shielding parameters. a multi-isotopomer analysis, including data from the 120 Sn 17 O and 120 Sn 18 O isotopomers, has been performed on the data. Born-Oppenheimer breakdown parameters were required in the fit and these parameters have been compared to those for the other Sn-chalcogenides.

UR - https://scholarsmine.mst.edu/chem_facwork/2080

UR - https://doi.org/10.1016/j.jms.2007.11.009

U2 - 10.1016/j.jms.2007.11.009

DO - 10.1016/j.jms.2007.11.009

M3 - Article

SN - 1096-083X

VL - 248

JO - Journal of Molecular Spectroscopy

JF - Journal of Molecular Spectroscopy

ER -

The ¹¹⁵Sn, ¹¹⁷Sn and ¹¹⁹Sn Nuclear Spin-rotation Constants in Stannous Monoxide, SnO, and a New Multi-isotopomer Analysis

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