Superoxide Oxidation of Hydroxy- and Keto-polyaromatics Including Internal Quinones

W. Li; Chariklia Sotiriou-Leventis; M. Saha; P. P. Fu; Roger W. Giese

doi:10.1080/00397919308020407

Superoxide Oxidation of Hydroxy- and Keto-polyaromatics Including Internal Quinones

W. Li
, Chariklia Sotiriou-Leventis
, M. Saha
, P. P. Fu
, Roger W. Giese

Missouri University of Science and Technology

Research output: Contribution to journal › Article › peer-review

Abstract

Aromatic 1,2-dicarboxylic acids can be obtained by KO2 oxidation of polyaromatics comprising analogs of 1-naphthol, sterically hindered alcohols and ketones, and, perhaps most interestingly, quinones fused on both sides to aromatic rings. A mechanism is presented to rationalize the formation of phthalic acid as the only major product from 5,12-naphthacenequinone.

Original language	American English
Journal	Synthetic Communications
DOIs	https://doi.org/10.1080/00397919308020407
State	Published - Jan 1 1993

Disciplines

Chemistry

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https://doi.org/10.1080/00397919308020407

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title = "Superoxide Oxidation of Hydroxy- and Keto-polyaromatics Including Internal Quinones",

abstract = " Aromatic 1,2-dicarboxylic acids can be obtained by KO2 oxidation of polyaromatics comprising analogs of 1-naphthol, sterically hindered alcohols and ketones, and, perhaps most interestingly, quinones fused on both sides to aromatic rings. A mechanism is presented to rationalize the formation of phthalic acid as the only major product from 5,12-naphthacenequinone.",

author = "W. Li and Chariklia Sotiriou-Leventis and M. Saha and Fu, \{P. P.\} and Giese, \{Roger W.\}",

year = "1993",

month = jan,

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doi = "10.1080/00397919308020407",

language = "American English",

journal = "Synthetic Communications",

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T1 - Superoxide Oxidation of Hydroxy- and Keto-polyaromatics Including Internal Quinones

AU - Li, W.

AU - Sotiriou-Leventis, Chariklia

AU - Saha, M.

AU - Fu, P. P.

AU - Giese, Roger W.

PY - 1993/1/1

Y1 - 1993/1/1

N2 - Aromatic 1,2-dicarboxylic acids can be obtained by KO2 oxidation of polyaromatics comprising analogs of 1-naphthol, sterically hindered alcohols and ketones, and, perhaps most interestingly, quinones fused on both sides to aromatic rings. A mechanism is presented to rationalize the formation of phthalic acid as the only major product from 5,12-naphthacenequinone.

AB - Aromatic 1,2-dicarboxylic acids can be obtained by KO2 oxidation of polyaromatics comprising analogs of 1-naphthol, sterically hindered alcohols and ketones, and, perhaps most interestingly, quinones fused on both sides to aromatic rings. A mechanism is presented to rationalize the formation of phthalic acid as the only major product from 5,12-naphthacenequinone.

UR - https://scholarsmine.mst.edu/chem_facwork/517

UR - https://doi.org/10.1080/00397919308020407

U2 - 10.1080/00397919308020407

DO - 10.1080/00397919308020407

M3 - Article

JO - Synthetic Communications

JF - Synthetic Communications

ER -

Superoxide Oxidation of Hydroxy- and Keto-polyaromatics Including Internal Quinones

Abstract

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