Some Studies on Dicyclohexylammonium Hydridoundecacarbonyltriferate

R. B. King; G. S. Chorghade; N. K. Bhattacharyya; E. M. Holt; Gary J. Long

doi:10.1016/0022-328X(91)83047-8

Some Studies on Dicyclohexylammonium Hydridoundecacarbonyltriferate

R. B. King
, G. S. Chorghade
, N. K. Bhattacharyya
, E. M. Holt
, Gary J. Long

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The salt [CxNH2][HFe3(CO)11]·OEt2 (Cx = cyclohexyl, Et = ethyl) was isolated from Cx2NBBr2/Na2Fe2(CO)8/Et2O and was shown by X-ray diffraction (monoclinic, P21/a: a = 17.449(5), b = 16.345(5), c =13.466(4) Å, β = 118.45(2)0, Z = 4) to contain the expected Cx2NH+2 and HFe3(CO)-11 ions as well as the diethyl ether. In each Cx2NH+2 cation one hydrogen atom is hydrogen bonded to the bridging CO oxygen of the HFe3(CO)11 anion whereas the other hydrogen atom is hydrogen bonded to the diethyl ether. The Mössbauer effect spectral parameters (δ, ΔEQ, Γ, area ratios) of [Cx2NH2][HFe3(CO)11] at 295 and 78 K are closely related to those of Fe3(CO)12. © 1991.

Original language	American English
Journal	Journal of Organometallic Chemistry
DOIs	https://doi.org/10.1016/0022-328X(91)83047-8
State	Published - Jan 1 1991

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Chemistry

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@article{096ea44cf01e4940b7eb2b5f05792a4f,

title = "Some Studies on Dicyclohexylammonium Hydridoundecacarbonyltriferate",

abstract = " The salt [CxNH2][HFe3(CO)11]·OEt2 (Cx = cyclohexyl, Et = ethyl) was isolated from Cx2NBBr2/Na2Fe2(CO)8/Et2O and was shown by X-ray diffraction (monoclinic, P21/a: a = 17.449(5), b = 16.345(5), c =13.466(4) {\AA}, β = 118.45(2)0, Z = 4) to contain the expected Cx2NH+2 and HFe3(CO)-11 ions as well as the diethyl ether. In each Cx2NH+2 cation one hydrogen atom is hydrogen bonded to the bridging CO oxygen of the HFe3(CO)11 anion whereas the other hydrogen atom is hydrogen bonded to the diethyl ether. The M{\"o}ssbauer effect spectral parameters (δ, ΔEQ, Γ, area ratios) of [Cx2NH2][HFe3(CO)11] at 295 and 78 K are closely related to those of Fe3(CO)12. {\textcopyright} 1991.",

author = "King, \{R. B.\} and Chorghade, \{G. S.\} and Bhattacharyya, \{N. K.\} and Holt, \{E. M.\} and Long, \{Gary J.\}",

year = "1991",

month = jan,

day = "1",

doi = "10.1016/0022-328X(91)83047-8",

language = "American English",

journal = "Journal of Organometallic Chemistry",

}

TY - JOUR

T1 - Some Studies on Dicyclohexylammonium Hydridoundecacarbonyltriferate

AU - King, R. B.

AU - Chorghade, G. S.

AU - Bhattacharyya, N. K.

AU - Holt, E. M.

AU - Long, Gary J.

PY - 1991/1/1

Y1 - 1991/1/1

N2 - The salt [CxNH2][HFe3(CO)11]·OEt2 (Cx = cyclohexyl, Et = ethyl) was isolated from Cx2NBBr2/Na2Fe2(CO)8/Et2O and was shown by X-ray diffraction (monoclinic, P21/a: a = 17.449(5), b = 16.345(5), c =13.466(4) Å, β = 118.45(2)0, Z = 4) to contain the expected Cx2NH+2 and HFe3(CO)-11 ions as well as the diethyl ether. In each Cx2NH+2 cation one hydrogen atom is hydrogen bonded to the bridging CO oxygen of the HFe3(CO)11 anion whereas the other hydrogen atom is hydrogen bonded to the diethyl ether. The Mössbauer effect spectral parameters (δ, ΔEQ, Γ, area ratios) of [Cx2NH2][HFe3(CO)11] at 295 and 78 K are closely related to those of Fe3(CO)12. © 1991.

AB - The salt [CxNH2][HFe3(CO)11]·OEt2 (Cx = cyclohexyl, Et = ethyl) was isolated from Cx2NBBr2/Na2Fe2(CO)8/Et2O and was shown by X-ray diffraction (monoclinic, P21/a: a = 17.449(5), b = 16.345(5), c =13.466(4) Å, β = 118.45(2)0, Z = 4) to contain the expected Cx2NH+2 and HFe3(CO)-11 ions as well as the diethyl ether. In each Cx2NH+2 cation one hydrogen atom is hydrogen bonded to the bridging CO oxygen of the HFe3(CO)11 anion whereas the other hydrogen atom is hydrogen bonded to the diethyl ether. The Mössbauer effect spectral parameters (δ, ΔEQ, Γ, area ratios) of [Cx2NH2][HFe3(CO)11] at 295 and 78 K are closely related to those of Fe3(CO)12. © 1991.

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UR - https://doi.org/10.1016/0022-328X(91)83047-8

U2 - 10.1016/0022-328X(91)83047-8

DO - 10.1016/0022-328X(91)83047-8

M3 - Article

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

ER -

Some Studies on Dicyclohexylammonium Hydridoundecacarbonyltriferate

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