Solubility of Methane, Propane, and N-Hexane in the Water-Sulfuric Acid System At 283-343 K

Alexander I. Lutsyk; Elisey S. Rudakov; G. G. Gundilovich; Vadym Mochalin

Solubility of Methane, Propane, and N-Hexane in the Water-Sulfuric Acid System At 283-343 K

Alexander I. Lutsyk
, Elisey S. Rudakov
, G. G. Gundilovich
, Vadym Mochalin

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The limiting distribution coefficients α = lim([HC] _g / [HC] _sln ) (HC stands for "hydrocarbon") corresponding to [HC] _g → 0 were measured for solutions of methane, propane, and n-hexane in the water-sulfuric acid system at acid concentrations of 0 to 100% in the temperature range 283-343 K. Substrate structure, solvent composition, and temperature effects on the solubility were studied. In the studied medium composition and temperature ranges, the equation (logα) ≡ logα ^E - φ _W logα _W - φ _A logα _A = Lφ(V ^E /V), where φ _W and φ _A are the volume fractions of water and acid, respectively, and V ^E is the excess volume, describes experimental data much more accurately than a similar equation with (logα) ^E in mole fractions.

Original language	American English
Pages (from-to)	390-394
Number of pages	5
Journal	Russian Journal of Physical Chemistry A
Volume	73
Issue number	3
State	Published - Jan 1 1999

Disciplines

Chemistry

Cite this

@article{4b91013313024cc6a853c63884c485e3,

title = "Solubility of Methane, Propane, and N-Hexane in the Water-Sulfuric Acid System At 283-343 K",

abstract = " The limiting distribution coefficients α = lim([HC] g / [HC] sln ) (HC stands for {"}hydrocarbon{"}) corresponding to [HC] g → 0 were measured for solutions of methane, propane, and n-hexane in the water-sulfuric acid system at acid concentrations of 0 to 100\% in the temperature range 283-343 K. Substrate structure, solvent composition, and temperature effects on the solubility were studied. In the studied medium composition and temperature ranges, the equation (logα) ≡ logα E - φ W logα W - φ A logα A = Lφ(V E /V), where φ W and φ A are the volume fractions of water and acid, respectively, and V E is the excess volume, describes experimental data much more accurately than a similar equation with (logα) E in mole fractions.",

author = "Lutsyk, \{Alexander I.\} and Rudakov, \{Elisey S.\} and Gundilovich, \{G. G.\} and Vadym Mochalin",

year = "1999",

month = jan,

day = "1",

language = "American English",

volume = "73",

pages = "390--394",

journal = "Russian Journal of Physical Chemistry A",

issn = "0036-0244",

number = "3",

}

TY - JOUR

T1 - Solubility of Methane, Propane, and N-Hexane in the Water-Sulfuric Acid System At 283-343 K

AU - Lutsyk, Alexander I.

AU - Rudakov, Elisey S.

AU - Gundilovich, G. G.

AU - Mochalin, Vadym

PY - 1999/1/1

Y1 - 1999/1/1

N2 - The limiting distribution coefficients α = lim([HC] g / [HC] sln ) (HC stands for "hydrocarbon") corresponding to [HC] g → 0 were measured for solutions of methane, propane, and n-hexane in the water-sulfuric acid system at acid concentrations of 0 to 100% in the temperature range 283-343 K. Substrate structure, solvent composition, and temperature effects on the solubility were studied. In the studied medium composition and temperature ranges, the equation (logα) ≡ logα E - φ W logα W - φ A logα A = Lφ(V E /V), where φ W and φ A are the volume fractions of water and acid, respectively, and V E is the excess volume, describes experimental data much more accurately than a similar equation with (logα) E in mole fractions.

AB - The limiting distribution coefficients α = lim([HC] g / [HC] sln ) (HC stands for "hydrocarbon") corresponding to [HC] g → 0 were measured for solutions of methane, propane, and n-hexane in the water-sulfuric acid system at acid concentrations of 0 to 100% in the temperature range 283-343 K. Substrate structure, solvent composition, and temperature effects on the solubility were studied. In the studied medium composition and temperature ranges, the equation (logα) ≡ logα E - φ W logα W - φ A logα A = Lφ(V E /V), where φ W and φ A are the volume fractions of water and acid, respectively, and V E is the excess volume, describes experimental data much more accurately than a similar equation with (logα) E in mole fractions.

UR - https://www.scopus.com/pages/publications/0012729309

UR - https://www.scopus.com/pages/publications/0012729309#tab=citedBy

M3 - Article

SN - 0036-0244

VL - 73

SP - 390

EP - 394

JO - Russian Journal of Physical Chemistry A

JF - Russian Journal of Physical Chemistry A

IS - 3

ER -

Solubility of Methane, Propane, and N-Hexane in the Water-Sulfuric Acid System At 283-343 K

Abstract

Disciplines

Other files and links

Fingerprint

Cite this