Rate Constants for the Reactions of N(²D) Atoms with O₂, H₂ and HF

Philip D. Whitefield; Floyd E. Hovis

doi:10.1016/0009-2614(87)85189-8

Rate Constants for the Reactions of N(²D) Atoms with O₂, H₂ and HF

Philip D. Whitefield
, Floyd E. Hovis

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The rate constants k1,k2 and k3 for the reactions of N(2D) atoms with H2, HF, and O2, measured at room temperature in a discharge-flow atomic-resonance-absorption apparatus, have been determined to be (1.8 ± 0.8)×10-12, (1.0±0.3) × 10-12 and (6.6± 1.0) × 10-12cm3s-1, respectively. Previously published data on k1 and k3 exist and there is good agreement between those studies and that described herein. © 1987.

Original language	American English
Journal	Chemical Physics Letters
DOIs	https://doi.org/10.1016/0009-2614(87)85189-8
State	Published - Jan 1 1987

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Chemistry

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title = "Rate Constants for the Reactions of N(²D) Atoms with O₂, H₂ and HF",

abstract = " The rate constants k1,k2 and k3 for the reactions of N(2D) atoms with H2, HF, and O2, measured at room temperature in a discharge-flow atomic-resonance-absorption apparatus, have been determined to be (1.8 ± 0.8)×10-12, (1.0±0.3) × 10-12 and (6.6± 1.0) × 10-12cm3s-1, respectively. Previously published data on k1 and k3 exist and there is good agreement between those studies and that described herein. {\textcopyright} 1987.",

author = "Whitefield, \{Philip D.\} and Hovis, \{Floyd E.\}",

year = "1987",

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doi = "10.1016/0009-2614(87)85189-8",

language = "American English",

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T1 - Rate Constants for the Reactions of N(²D) Atoms with O₂, H₂ and HF

AU - Whitefield, Philip D.

AU - Hovis, Floyd E.

PY - 1987/1/1

Y1 - 1987/1/1

N2 - The rate constants k1,k2 and k3 for the reactions of N(2D) atoms with H2, HF, and O2, measured at room temperature in a discharge-flow atomic-resonance-absorption apparatus, have been determined to be (1.8 ± 0.8)×10-12, (1.0±0.3) × 10-12 and (6.6± 1.0) × 10-12cm3s-1, respectively. Previously published data on k1 and k3 exist and there is good agreement between those studies and that described herein. © 1987.

AB - The rate constants k1,k2 and k3 for the reactions of N(2D) atoms with H2, HF, and O2, measured at room temperature in a discharge-flow atomic-resonance-absorption apparatus, have been determined to be (1.8 ± 0.8)×10-12, (1.0±0.3) × 10-12 and (6.6± 1.0) × 10-12cm3s-1, respectively. Previously published data on k1 and k3 exist and there is good agreement between those studies and that described herein. © 1987.

UR - https://scholarsmine.mst.edu/chem_facwork/1280

UR - https://doi.org/10.1016/0009-2614(87)85189-8

U2 - 10.1016/0009-2614(87)85189-8

DO - 10.1016/0009-2614(87)85189-8

M3 - Article

JO - Chemical Physics Letters

JF - Chemical Physics Letters

ER -

Rate Constants for the Reactions of N(²D) Atoms with O₂, H₂ and HF

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