Products Formed in an Electron Capture Detector from Various Gas Chromatographic Solutes

Shubhender Kapila; Walter A. Aue

doi:10.1016/S0021-9673(00)85293-0

Products Formed in an Electron Capture Detector from Various Gas Chromatographic Solutes

Shubhender Kapila
, Walter A. Aue

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

A variety of neutral, volatile, electron-capturing products was found to originate in the electron capture detector from certain pesticides and similiratiy structured analytes, such as the hexachlorocyclohexanes, penta- and tetrachloronitrobenzene, and various polychlorobenzenes. Some of these unexpected products have been tentatively edentified by gas chromatographic retention data. According to these, product patterns arise from the loss of halide and/or nitro groups. These patterns are indicative of the analyte and can potentially be used to confirm peak identity in the lower picogram range, and determine the configuration of isomers. © 1978.

Original language	American English
Journal	Journal of Chromatography A
DOIs	https://doi.org/10.1016/S0021-9673(00)85293-0
State	Published - Jan 1 1978

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Chemistry

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title = "Products Formed in an Electron Capture Detector from Various Gas Chromatographic Solutes",

abstract = " A variety of neutral, volatile, electron-capturing products was found to originate in the electron capture detector from certain pesticides and similiratiy structured analytes, such as the hexachlorocyclohexanes, penta- and tetrachloronitrobenzene, and various polychlorobenzenes. Some of these unexpected products have been tentatively edentified by gas chromatographic retention data. According to these, product patterns arise from the loss of halide and/or nitro groups. These patterns are indicative of the analyte and can potentially be used to confirm peak identity in the lower picogram range, and determine the configuration of isomers. {\textcopyright} 1978.",

author = "Shubhender Kapila and Aue, \{Walter A.\}",

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doi = "10.1016/S0021-9673(00)85293-0",

language = "American English",

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AU - Aue, Walter A.

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N2 - A variety of neutral, volatile, electron-capturing products was found to originate in the electron capture detector from certain pesticides and similiratiy structured analytes, such as the hexachlorocyclohexanes, penta- and tetrachloronitrobenzene, and various polychlorobenzenes. Some of these unexpected products have been tentatively edentified by gas chromatographic retention data. According to these, product patterns arise from the loss of halide and/or nitro groups. These patterns are indicative of the analyte and can potentially be used to confirm peak identity in the lower picogram range, and determine the configuration of isomers. © 1978.

AB - A variety of neutral, volatile, electron-capturing products was found to originate in the electron capture detector from certain pesticides and similiratiy structured analytes, such as the hexachlorocyclohexanes, penta- and tetrachloronitrobenzene, and various polychlorobenzenes. Some of these unexpected products have been tentatively edentified by gas chromatographic retention data. According to these, product patterns arise from the loss of halide and/or nitro groups. These patterns are indicative of the analyte and can potentially be used to confirm peak identity in the lower picogram range, and determine the configuration of isomers. © 1978.

UR - https://scholarsmine.mst.edu/chem_facwork/1299

UR - https://doi.org/10.1016/S0021-9673(00)85293-0

U2 - 10.1016/S0021-9673(00)85293-0

DO - 10.1016/S0021-9673(00)85293-0

M3 - Article

JO - Journal of Chromatography A

JF - Journal of Chromatography A

ER -

Products Formed in an Electron Capture Detector from Various Gas Chromatographic Solutes

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