Photoelectrochemistry of the Thallic/Thallous Couple

Jay A. Switzer

doi:10.1149/1.2123481

Photoelectrochemistry of the Thallic/Thallous Couple

Jay A. Switzer

Chemistry

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Abstract

<p> Liquid&hyphen;junction photovoltaic and photoelectrosynthetic applications of the thallic/thallous couple have been investigated. In the liquid&hyphen;junction photovoltaic mode the redox couple produces large photovoltages with several semiconductors ( , , , and ), and does not absorb appreciable semiconductor ultra&hyphen;bandgap light. The couple also shows photoelectrosynthetic utility, since the thallic ion is a selective two&hyphen;electron oxidizing agent for a variety of organic substrates. Preliminary work on the photoassisted epoxidation of propylene at n&hyphen;type semiconductor electrodes and powders ( , , and ) is discussed.</p>

Original language	American English
Journal	Journal of the Electrochemical Society
DOIs	https://doi.org/10.1149/1.2123481
State	Published - Jan 1 1982

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Chemistry

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title = "Photoelectrochemistry of the Thallic/Thallous Couple",

abstract = " Liquid\&hyphen;junction photovoltaic and photoelectrosynthetic applications of the thallic/thallous couple have been investigated. In the liquid\&hyphen;junction photovoltaic mode the redox couple produces large photovoltages with several semiconductors ( , , , and ), and does not absorb appreciable semiconductor ultra\&hyphen;bandgap light. The couple also shows photoelectrosynthetic utility, since the thallic ion is a selective two\&hyphen;electron oxidizing agent for a variety of organic substrates. Preliminary work on the photoassisted epoxidation of propylene at n\&hyphen;type semiconductor electrodes and powders ( , , and ) is discussed.",

author = "Switzer, \{Jay A.\}",

year = "1982",

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doi = "10.1149/1.2123481",

language = "American English",

journal = "Journal of the Electrochemical Society",

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AU - Switzer, Jay A.

PY - 1982/1/1

Y1 - 1982/1/1

N2 - Liquid&hyphen;junction photovoltaic and photoelectrosynthetic applications of the thallic/thallous couple have been investigated. In the liquid&hyphen;junction photovoltaic mode the redox couple produces large photovoltages with several semiconductors ( , , , and ), and does not absorb appreciable semiconductor ultra&hyphen;bandgap light. The couple also shows photoelectrosynthetic utility, since the thallic ion is a selective two&hyphen;electron oxidizing agent for a variety of organic substrates. Preliminary work on the photoassisted epoxidation of propylene at n&hyphen;type semiconductor electrodes and powders ( , , and ) is discussed.

AB - Liquid&hyphen;junction photovoltaic and photoelectrosynthetic applications of the thallic/thallous couple have been investigated. In the liquid&hyphen;junction photovoltaic mode the redox couple produces large photovoltages with several semiconductors ( , , , and ), and does not absorb appreciable semiconductor ultra&hyphen;bandgap light. The couple also shows photoelectrosynthetic utility, since the thallic ion is a selective two&hyphen;electron oxidizing agent for a variety of organic substrates. Preliminary work on the photoassisted epoxidation of propylene at n&hyphen;type semiconductor electrodes and powders ( , , and ) is discussed.

UR - https://scholarsmine.mst.edu/chem_facwork/594

UR - https://doi.org/10.1149/1.2123481

U2 - 10.1149/1.2123481

DO - 10.1149/1.2123481

M3 - Article

SN - 1945-7111

JO - Journal of the Electrochemical Society

JF - Journal of the Electrochemical Society

ER -

Photoelectrochemistry of the Thallic/Thallous Couple

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