Permeation of Several Gases through Elastomers, with Emphasis on the Deuterium/hydrogen Pair

M. (Mark) W. Fitch; W. J. Koros; R. L. Nolen; J. R. Carnes

doi:10.1002/app.1993.070470610

Permeation of Several Gases through Elastomers, with Emphasis on the Deuterium/hydrogen Pair

M. (Mark) W. Fitch
, W. J. Koros
, R. L. Nolen
, J. R. Carnes

Missouri Univeristy of Science and Technology

Research output: Contribution to journal › Article › peer-review

Abstract

<p> The Diffusion and Permeation Coefficients for He, H2, D2, O2, and N2 in a Variety of Elastomers Were Measured by Simple Manometric Methods. the Elastomers Studied Were Butyl Rubber; Hypalon® 40 and 45; Viton® E60 and GF; Hydrin® 100 and Filled Hydrin® 100; Kraton® G, FG, and KG VTEOS; EPDM; Epoxidized Natural Rubber; and Neoprene. Consistent with Earlier Studies, Elastomers with Higher Glass Transition Temperatures Exhibited Lower Diffusion Coefficients. the Ratio of Diffusion Coefficients of the Hydrogen Isotope Pair Differed from the Purely Molecular&hyphen;weight&hyphen;based Prediction. Deuterium's Slightly Smaller Size Relative to Hydrogen is Consistent with Observed Deviations from the Molecular&hyphen;weight&hyphen;based Diffusion Coefficient Ratio. © 1993 John Wiley & Sons, Inc. Copyright © 1993 John Wiley & Sons, Inc.</p>

Original language	American English
Journal	Journal of Applied Polymer Science
Volume	47
DOIs	https://doi.org/10.1002/app.1993.070470610
State	Published - Jan 1 1993
Externally published	Yes

Disciplines

Architectural Engineering
Civil and Environmental Engineering

Access to Document

10.1002/app.1993.070470610License: Unspecified

Permeation of Several Gases through Elastomers with Emphasis onFinal published version, 975 KBLicense: Unspecified

Cite this

@article{fc7282b590414c4395702333ff827949,

title = "Permeation of Several Gases through Elastomers, with Emphasis on the Deuterium/hydrogen Pair",

abstract = " The Diffusion and Permeation Coefficients for He, H2, D2, O2, and N2 in a Variety of Elastomers Were Measured by Simple Manometric Methods. the Elastomers Studied Were Butyl Rubber; Hypalon\® 40 and 45; Viton\® E60 and GF; Hydrin\® 100 and Filled Hydrin\® 100; Kraton\® G, FG, and KG VTEOS; EPDM; Epoxidized Natural Rubber; and Neoprene. Consistent with Earlier Studies, Elastomers with Higher Glass Transition Temperatures Exhibited Lower Diffusion Coefficients. the Ratio of Diffusion Coefficients of the Hydrogen Isotope Pair Differed from the Purely Molecular\&hyphen;weight\&hyphen;based Prediction. Deuterium's Slightly Smaller Size Relative to Hydrogen is Consistent with Observed Deviations from the Molecular\&hyphen;weight\&hyphen;based Diffusion Coefficient Ratio. \© 1993 John Wiley \& Sons, Inc. Copyright \© 1993 John Wiley \& Sons, Inc.",

author = "Fitch, \{M. (Mark) W.\} and Koros, \{W. J.\} and Nolen, \{R. L.\} and Carnes, \{J. R.\}",

year = "1993",

month = jan,

day = "1",

doi = "10.1002/app.1993.070470610",

language = "American English",

volume = "47",

journal = "Journal of Applied Polymer Science",

issn = "1097-4628",

}

TY - JOUR

T1 - Permeation of Several Gases through Elastomers, with Emphasis on the Deuterium/hydrogen Pair

AU - Fitch, M. (Mark) W.

AU - Koros, W. J.

AU - Nolen, R. L.

AU - Carnes, J. R.

PY - 1993/1/1

Y1 - 1993/1/1

N2 - The Diffusion and Permeation Coefficients for He, H2, D2, O2, and N2 in a Variety of Elastomers Were Measured by Simple Manometric Methods. the Elastomers Studied Were Butyl Rubber; Hypalon® 40 and 45; Viton® E60 and GF; Hydrin® 100 and Filled Hydrin® 100; Kraton® G, FG, and KG VTEOS; EPDM; Epoxidized Natural Rubber; and Neoprene. Consistent with Earlier Studies, Elastomers with Higher Glass Transition Temperatures Exhibited Lower Diffusion Coefficients. the Ratio of Diffusion Coefficients of the Hydrogen Isotope Pair Differed from the Purely Molecular&hyphen;weight&hyphen;based Prediction. Deuterium's Slightly Smaller Size Relative to Hydrogen is Consistent with Observed Deviations from the Molecular&hyphen;weight&hyphen;based Diffusion Coefficient Ratio. © 1993 John Wiley & Sons, Inc. Copyright © 1993 John Wiley & Sons, Inc.

AB - The Diffusion and Permeation Coefficients for He, H2, D2, O2, and N2 in a Variety of Elastomers Were Measured by Simple Manometric Methods. the Elastomers Studied Were Butyl Rubber; Hypalon® 40 and 45; Viton® E60 and GF; Hydrin® 100 and Filled Hydrin® 100; Kraton® G, FG, and KG VTEOS; EPDM; Epoxidized Natural Rubber; and Neoprene. Consistent with Earlier Studies, Elastomers with Higher Glass Transition Temperatures Exhibited Lower Diffusion Coefficients. the Ratio of Diffusion Coefficients of the Hydrogen Isotope Pair Differed from the Purely Molecular&hyphen;weight&hyphen;based Prediction. Deuterium's Slightly Smaller Size Relative to Hydrogen is Consistent with Observed Deviations from the Molecular&hyphen;weight&hyphen;based Diffusion Coefficient Ratio. © 1993 John Wiley & Sons, Inc. Copyright © 1993 John Wiley & Sons, Inc.

UR - https://scholarsmine.mst.edu/civarc_enveng_facwork/2422

U2 - 10.1002/app.1993.070470610

DO - 10.1002/app.1993.070470610

M3 - Article

SN - 1097-4628

VL - 47

JO - Journal of Applied Polymer Science

JF - Journal of Applied Polymer Science

ER -

Permeation of Several Gases through Elastomers, with Emphasis on the Deuterium/hydrogen Pair

Abstract

Disciplines

Access to Document

Other files and links

Fingerprint

Cite this