Gallium Containing Glass Polyalkenoate Anti-Cancerous Bone Cements: Glass Characterization and Physical Properties

A. W. Wren; A. Coughlan; L. Placek; Mark R. Towler

doi:10.1007/s10856-012-4624-4

Gallium Containing Glass Polyalkenoate Anti-Cancerous Bone Cements: Glass Characterization and Physical Properties

A. W. Wren
, A. Coughlan
, L. Placek
, Mark R. Towler

Missouri University of Science and Technology

Research output: Contribution to journal › Article › peer-review

Abstract

A gallium (Ga) glass series (0.48SiO ₂ -0.40ZnO-0.12CaO, with 0.08 mol% substitution for ZnO) was developed to formulate a Ga-containing Glass Polyalkenoate Cement (GPC) series. Network connectivity (NC) and X-ray Photoelectron Spectroscopy (XPS) was employed to investigate the role of Ga ³⁺ in the glass, where it is assumed to act as a network modifier. Ga-GPC series was formulated with E9 and E11 polyacrylic acid (PAA) at 50, 55 and 60 wt% additions. E11 working times (T _w ) ranged from 68 to 96 s (Lcon.) and 106 s for the Ga-GPCs (LGa-1 and LGa-2). Setting times (T _s ) ranged from 104 to 226 s (Lcon.) and 211 s for LGa-1 and LGa-2. Compression (δc) and biaxial flexural (δf) testing were conducted where Lcon. increased from 62 to 68 MPa, LGa-1 from 14 to 42 MPa and LGa-2 from 20 to 47 MPa in δc over 1-30 days. δf testing revealed that Lcon. increased from 29 to 42 MPa, LGa-1 from 7 to 32 MPa and LGa-2 from 12 to 36 MPa over 1-30 days. © 2012 Springer Science+Business Media, LLC.

Original language	American English
Journal	Journal of Materials Science: Materials in Medicine
Volume	23
DOIs	https://doi.org/10.1007/s10856-012-4624-4
State	Published - Aug 1 2012

Disciplines

Biochemical and Biomolecular Engineering
Biomedical Devices and Instrumentation
Chemical Engineering

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@article{1513c64c839244dd9f700e456ff7fbcf,

title = "Gallium Containing Glass Polyalkenoate Anti-Cancerous Bone Cements: Glass Characterization and Physical Properties",

abstract = " A gallium (Ga) glass series (0.48SiO 2 -0.40ZnO-0.12CaO, with 0.08 mol\% substitution for ZnO) was developed to formulate a Ga-containing Glass Polyalkenoate Cement (GPC) series. Network connectivity (NC) and X-ray Photoelectron Spectroscopy (XPS) was employed to investigate the role of Ga 3+ in the glass, where it is assumed to act as a network modifier. Ga-GPC series was formulated with E9 and E11 polyacrylic acid (PAA) at 50, 55 and 60 wt\% additions. E11 working times (T w ) ranged from 68 to 96 s (Lcon.) and 106 s for the Ga-GPCs (LGa-1 and LGa-2). Setting times (T s ) ranged from 104 to 226 s (Lcon.) and 211 s for LGa-1 and LGa-2. Compression (δc) and biaxial flexural (δf) testing were conducted where Lcon. increased from 62 to 68 MPa, LGa-1 from 14 to 42 MPa and LGa-2 from 20 to 47 MPa in δc over 1-30 days. δf testing revealed that Lcon. increased from 29 to 42 MPa, LGa-1 from 7 to 32 MPa and LGa-2 from 12 to 36 MPa over 1-30 days. {\textcopyright} 2012 Springer Science+Business Media, LLC.",

author = "Wren, \{A. W.\} and A. Coughlan and L. Placek and Towler, \{Mark R.\}",

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T1 - Gallium Containing Glass Polyalkenoate Anti-Cancerous Bone Cements: Glass Characterization and Physical Properties

AU - Wren, A. W.

AU - Coughlan, A.

AU - Placek, L.

AU - Towler, Mark R.

PY - 2012/8/1

Y1 - 2012/8/1

N2 - A gallium (Ga) glass series (0.48SiO 2 -0.40ZnO-0.12CaO, with 0.08 mol% substitution for ZnO) was developed to formulate a Ga-containing Glass Polyalkenoate Cement (GPC) series. Network connectivity (NC) and X-ray Photoelectron Spectroscopy (XPS) was employed to investigate the role of Ga 3+ in the glass, where it is assumed to act as a network modifier. Ga-GPC series was formulated with E9 and E11 polyacrylic acid (PAA) at 50, 55 and 60 wt% additions. E11 working times (T w ) ranged from 68 to 96 s (Lcon.) and 106 s for the Ga-GPCs (LGa-1 and LGa-2). Setting times (T s ) ranged from 104 to 226 s (Lcon.) and 211 s for LGa-1 and LGa-2. Compression (δc) and biaxial flexural (δf) testing were conducted where Lcon. increased from 62 to 68 MPa, LGa-1 from 14 to 42 MPa and LGa-2 from 20 to 47 MPa in δc over 1-30 days. δf testing revealed that Lcon. increased from 29 to 42 MPa, LGa-1 from 7 to 32 MPa and LGa-2 from 12 to 36 MPa over 1-30 days. © 2012 Springer Science+Business Media, LLC.

AB - A gallium (Ga) glass series (0.48SiO 2 -0.40ZnO-0.12CaO, with 0.08 mol% substitution for ZnO) was developed to formulate a Ga-containing Glass Polyalkenoate Cement (GPC) series. Network connectivity (NC) and X-ray Photoelectron Spectroscopy (XPS) was employed to investigate the role of Ga 3+ in the glass, where it is assumed to act as a network modifier. Ga-GPC series was formulated with E9 and E11 polyacrylic acid (PAA) at 50, 55 and 60 wt% additions. E11 working times (T w ) ranged from 68 to 96 s (Lcon.) and 106 s for the Ga-GPCs (LGa-1 and LGa-2). Setting times (T s ) ranged from 104 to 226 s (Lcon.) and 211 s for LGa-1 and LGa-2. Compression (δc) and biaxial flexural (δf) testing were conducted where Lcon. increased from 62 to 68 MPa, LGa-1 from 14 to 42 MPa and LGa-2 from 20 to 47 MPa in δc over 1-30 days. δf testing revealed that Lcon. increased from 29 to 42 MPa, LGa-1 from 7 to 32 MPa and LGa-2 from 12 to 36 MPa over 1-30 days. © 2012 Springer Science+Business Media, LLC.

UR - https://scholarsmine.mst.edu/che_bioeng_facwork/1155

U2 - 10.1007/s10856-012-4624-4

DO - 10.1007/s10856-012-4624-4

M3 - Article

C2 - 22684625

VL - 23

JO - Journal of Materials Science: Materials in Medicine

JF - Journal of Materials Science: Materials in Medicine

ER -

Gallium Containing Glass Polyalkenoate Anti-Cancerous Bone Cements: Glass Characterization and Physical Properties

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