Defect Chemistry of Mixed Ionic/electronic P-type Oxides

Harlan U. Anderson; X.-D. Zhou; Fatih Dogan

doi:10.1007/978-1-4020-2349-1_30

Defect Chemistry of Mixed Ionic/electronic P-type Oxides

Missouri University of Science and Technology

Research output: Contribution to journal › Article › peer-review

Abstract

The p-type perovskite structure oxides are finding use in a number of energy related applications. In particular they are being used as cathodes in fuel cells as well as dense oxygen separation membranes. The defect concentration and defect mobility determine the electrical properties. Since both of these are dependent upon the operating temperature and oxygen activity, it is important to understand how an oxide equilibrates with its environment. In this paper, a defect chemistry model for the oxidation-reduction behavior of p-type perovskites is reviewed with formulations in the (La,Sr)(Cr,Mn,Co,Fe)03 system being used as examples.

Original language	American English
Journal	Mixed Ionic Electronic Conducting Perovskites for Advanced Energy Systems
DOIs	https://doi.org/10.1007/978-1-4020-2349-1_30
State	Published - Jan 1 2004

Keywords

Oxidation-Reduction
Electrical Conductivity
Oxygen Vacancies

Disciplines

Materials Science and Engineering

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10.1007/978-1-4020-2349-1_30License: CC BY

https://doi.org/10.1007/978-1-4020-2349-1_30

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abstract = " The p-type perovskite structure oxides are finding use in a number of energy related applications. In particular they are being used as cathodes in fuel cells as well as dense oxygen separation membranes. The defect concentration and defect mobility determine the electrical properties. Since both of these are dependent upon the operating temperature and oxygen activity, it is important to understand how an oxide equilibrates with its environment. In this paper, a defect chemistry model for the oxidation-reduction behavior of p-type perovskites is reviewed with formulations in the (La,Sr)(Cr,Mn,Co,Fe)03 system being used as examples.",

keywords = "Oxidation-Reduction, Electrical Conductivity, Oxygen Vacancies",

author = "Anderson, \{Harlan U.\} and X.-D. Zhou and Fatih Dogan",

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T1 - Defect Chemistry of Mixed Ionic/electronic P-type Oxides

AU - Anderson, Harlan U.

AU - Zhou, X.-D.

AU - Dogan, Fatih

PY - 2004/1/1

Y1 - 2004/1/1

N2 - The p-type perovskite structure oxides are finding use in a number of energy related applications. In particular they are being used as cathodes in fuel cells as well as dense oxygen separation membranes. The defect concentration and defect mobility determine the electrical properties. Since both of these are dependent upon the operating temperature and oxygen activity, it is important to understand how an oxide equilibrates with its environment. In this paper, a defect chemistry model for the oxidation-reduction behavior of p-type perovskites is reviewed with formulations in the (La,Sr)(Cr,Mn,Co,Fe)03 system being used as examples.

AB - The p-type perovskite structure oxides are finding use in a number of energy related applications. In particular they are being used as cathodes in fuel cells as well as dense oxygen separation membranes. The defect concentration and defect mobility determine the electrical properties. Since both of these are dependent upon the operating temperature and oxygen activity, it is important to understand how an oxide equilibrates with its environment. In this paper, a defect chemistry model for the oxidation-reduction behavior of p-type perovskites is reviewed with formulations in the (La,Sr)(Cr,Mn,Co,Fe)03 system being used as examples.

KW - Oxidation-Reduction

KW - Electrical Conductivity

KW - Oxygen Vacancies

UR - https://scholarsmine.mst.edu/matsci_eng_facwork/628

UR - https://doi.org/10.1007/978-1-4020-2349-1_30

U2 - 10.1007/978-1-4020-2349-1_30

DO - 10.1007/978-1-4020-2349-1_30

M3 - Article

JO - Mixed Ionic Electronic Conducting Perovskites for Advanced Energy Systems

JF - Mixed Ionic Electronic Conducting Perovskites for Advanced Energy Systems

ER -

Defect Chemistry of Mixed Ionic/electronic P-type Oxides

Abstract

Keywords

Disciplines

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