Controlled Stoichiometry for Quaternary CuInₓGa₁₋ₓS₂ Chalcopyrite Nanoparticles from Single-source Precursors via Microwave Irradiation

C. Sun; J. S. Gardner; Gary J. Long; C. Bajracharya; A. Thurber; A. Punnoose; R. G. Rodriguez; J. J. Pak

doi:10.1021/cm100456t

Controlled Stoichiometry for Quaternary CuInₓGa₁₋ₓS₂ Chalcopyrite Nanoparticles from Single-source Precursors via Microwave Irradiation

C. Sun
, J. S. Gardner
, Gary J. Long
, C. Bajracharya
, A. Thurber
, A. Punnoose
, R. G. Rodriguez
, J. J. Pak

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

We report the synthesis of quaternary CuInxGa 1-xS2 (0 ≤x ≤1) chalcopyrite nanoparticles from decomposition of two molecular single source precursors (SSPs), (Ph 3P)2Cu(μ-SEt)2In(SEt)2 (1) and (Ph3P)2Cu(μ-SEt)2Ga(SEt)2 (2), via remicrowave irradiation. We were able to precisely control stoichiometry and bandgaps of quaternary CuInxGa1-xS2 nanoparticles ranging from 1.40 to 2.30 eV. © 2010 American Chemical Society.

Original language	American English
Journal	Chemistry of Materials
DOIs	https://doi.org/10.1021/cm100456t
State	Published - Jan 1 2010

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Chemistry

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title = "Controlled Stoichiometry for Quaternary CuInₓGa₁₋ₓS₂ Chalcopyrite Nanoparticles from Single-source Precursors via Microwave Irradiation",

abstract = " We report the synthesis of quaternary CuInxGa 1-xS2 (0 ≤x ≤1) chalcopyrite nanoparticles from decomposition of two molecular single source precursors (SSPs), (Ph 3P)2Cu(μ-SEt)2In(SEt)2 (1) and (Ph3P)2Cu(μ-SEt)2Ga(SEt)2 (2), via remicrowave irradiation. We were able to precisely control stoichiometry and bandgaps of quaternary CuInxGa1-xS2 nanoparticles ranging from 1.40 to 2.30 eV. {\textcopyright} 2010 American Chemical Society.",

author = "C. Sun and Gardner, \{J. S.\} and Long, \{Gary J.\} and C. Bajracharya and A. Thurber and A. Punnoose and Rodriguez, \{R. G.\} and Pak, \{J. J.\}",

year = "2010",

month = jan,

day = "1",

doi = "10.1021/cm100456t",

language = "American English",

journal = "Chemistry of Materials",

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TY - JOUR

T1 - Controlled Stoichiometry for Quaternary CuInₓGa₁₋ₓS₂ Chalcopyrite Nanoparticles from Single-source Precursors via Microwave Irradiation

AU - Sun, C.

AU - Gardner, J. S.

AU - Long, Gary J.

AU - Bajracharya, C.

AU - Thurber, A.

AU - Punnoose, A.

AU - Rodriguez, R. G.

AU - Pak, J. J.

PY - 2010/1/1

Y1 - 2010/1/1

N2 - We report the synthesis of quaternary CuInxGa 1-xS2 (0 ≤x ≤1) chalcopyrite nanoparticles from decomposition of two molecular single source precursors (SSPs), (Ph 3P)2Cu(μ-SEt)2In(SEt)2 (1) and (Ph3P)2Cu(μ-SEt)2Ga(SEt)2 (2), via remicrowave irradiation. We were able to precisely control stoichiometry and bandgaps of quaternary CuInxGa1-xS2 nanoparticles ranging from 1.40 to 2.30 eV. © 2010 American Chemical Society.

AB - We report the synthesis of quaternary CuInxGa 1-xS2 (0 ≤x ≤1) chalcopyrite nanoparticles from decomposition of two molecular single source precursors (SSPs), (Ph 3P)2Cu(μ-SEt)2In(SEt)2 (1) and (Ph3P)2Cu(μ-SEt)2Ga(SEt)2 (2), via remicrowave irradiation. We were able to precisely control stoichiometry and bandgaps of quaternary CuInxGa1-xS2 nanoparticles ranging from 1.40 to 2.30 eV. © 2010 American Chemical Society.

UR - https://scholarsmine.mst.edu/chem_facwork/915

UR - https://doi.org/10.1021/cm100456t

U2 - 10.1021/cm100456t

DO - 10.1021/cm100456t

M3 - Article

SN - 1520-5002

JO - Chemistry of Materials

JF - Chemistry of Materials

ER -

Controlled Stoichiometry for Quaternary CuInₓGa₁₋ₓS₂ Chalcopyrite Nanoparticles from Single-source Precursors via Microwave Irradiation

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