Chirped Pulse Fourier Transform Microwave Spectroscopy of 1,1,2,2-tetrafluoro-3-iodopropane

Garry S. Grubbs; William C. Bailey; Stephen A. Cooke

doi:10.1080/00268970903228741

Chirped Pulse Fourier Transform Microwave Spectroscopy of 1,1,2,2-tetrafluoro-3-iodopropane

Garry S. Grubbs
, William C. Bailey
, Stephen A. Cooke

Missouri University of Science and Technology

Research output: Contribution to journal › Article › peer-review

Abstract

The pure rotational spectra of the two lowest energy conformers of 1,1,2,2-tetrafluoro-3-iodopropane have been investigated between the frequency limits of 7.5 and 16 GHz using chirped pulse Fourier transform microwave spectroscopy. Quantum chemical calculations have been performed to aid the spectral analyses. For the trans – trans conformer, which is calculated to be the lowest in energy, a total of 135 transitions were recorded. For the gauche – gauche conformer a total of 286 transitions were recorded. in both cases the complete iodine nuclear quadrupole coupling tensor has been determined.

Original language	American English
Journal	Molecular Physics
Volume	107
DOIs	https://doi.org/10.1080/00268970903228741
State	Published - Jan 1 2009

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Chemistry

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https://doi.org/10.1080/00268970903228741

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title = "Chirped Pulse Fourier Transform Microwave Spectroscopy of 1,1,2,2-tetrafluoro-3-iodopropane",

abstract = " The pure rotational spectra of the two lowest energy conformers of 1,1,2,2-tetrafluoro-3-iodopropane have been investigated between the frequency limits of 7.5 and 16 GHz using chirped pulse Fourier transform microwave spectroscopy. Quantum chemical calculations have been performed to aid the spectral analyses. For the trans – trans conformer, which is calculated to be the lowest in energy, a total of 135 transitions were recorded. For the gauche – gauche conformer a total of 286 transitions were recorded. in both cases the complete iodine nuclear quadrupole coupling tensor has been determined.",

author = "Grubbs, \{Garry S.\} and Bailey, \{William C.\} and Cooke, \{Stephen A.\}",

year = "2009",

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doi = "10.1080/00268970903228741",

language = "American English",

volume = "107",

journal = "Molecular Physics",

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T1 - Chirped Pulse Fourier Transform Microwave Spectroscopy of 1,1,2,2-tetrafluoro-3-iodopropane

AU - Grubbs, Garry S.

AU - Bailey, William C.

AU - Cooke, Stephen A.

PY - 2009/1/1

Y1 - 2009/1/1

N2 - The pure rotational spectra of the two lowest energy conformers of 1,1,2,2-tetrafluoro-3-iodopropane have been investigated between the frequency limits of 7.5 and 16 GHz using chirped pulse Fourier transform microwave spectroscopy. Quantum chemical calculations have been performed to aid the spectral analyses. For the trans – trans conformer, which is calculated to be the lowest in energy, a total of 135 transitions were recorded. For the gauche – gauche conformer a total of 286 transitions were recorded. in both cases the complete iodine nuclear quadrupole coupling tensor has been determined.

AB - The pure rotational spectra of the two lowest energy conformers of 1,1,2,2-tetrafluoro-3-iodopropane have been investigated between the frequency limits of 7.5 and 16 GHz using chirped pulse Fourier transform microwave spectroscopy. Quantum chemical calculations have been performed to aid the spectral analyses. For the trans – trans conformer, which is calculated to be the lowest in energy, a total of 135 transitions were recorded. For the gauche – gauche conformer a total of 286 transitions were recorded. in both cases the complete iodine nuclear quadrupole coupling tensor has been determined.

UR - https://scholarsmine.mst.edu/chem_facwork/2298

UR - https://doi.org/10.1080/00268970903228741

U2 - 10.1080/00268970903228741

DO - 10.1080/00268970903228741

M3 - Article

SN - 1362-3028

VL - 107

JO - Molecular Physics

JF - Molecular Physics

ER -

Chirped Pulse Fourier Transform Microwave Spectroscopy of 1,1,2,2-tetrafluoro-3-iodopropane

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