Characterization of 20Na₂O·30((1−x)CaO·xSrO)·50P₂O₅ Glasses for a Resorbable Optical Fiber Application

Parker T. Freudenberger; Akira Saitoh; Hikaru Ikeda; Md Shibab Adnan; Hiromichi Takebe; Shingo Nakane; Chang-Soo Kim; Richard K. Brow

doi:10.1111/ijag.13106

Characterization of 20Na₂O·30((1−x)CaO·xSrO)·50P₂O₅ Glasses for a Resorbable Optical Fiber Application

Parker T. Freudenberger
, Akira Saitoh
, Hikaru Ikeda
, Md Shibab Adnan
, Hiromichi Takebe
, Shingo Nakane
, Chang-Soo Kim
, Richard K. Brow

Research output: Contribution to journal › Article › peer-review

Abstract

Resorbable glasses with nominal molar compositions of 20Na ₂ O·30[(1−x)CaO·xSrO]·50P ₂ O ₅ , where x = 0, 0.25, 0.50, 0.75, and 1, were prepared and characterized. With the replacement of CaO by SrO, the molar volume, refractive index, and coefficient of thermal expansion increased, and the glass transition temperature, crystallization temperature, and viscosity decreased. The replacement of CaO by SrO decreased the dissolution rate in 37°C water by nearly an order of magnitude. Resorbable glass fibers drawn from melts of the 20Na ₂ O·30CaO·50P ₂ O ₅ glass exhibited decreasing transmission of laser light (632 nm) in a predictable way as the fiber dissolved in a phosphate buffer solution. This demonstrated that these glasses could be used to produce resorbable fibers for temporary biosensing or therapeutic applications.

Original language	American English
Pages (from-to)	378-390
Number of pages	13
Journal	International Journal of Applied Glass Science
Volume	10
Issue number	3
DOIs	https://doi.org/10.1111/ijag.13106
State	Published - Jul 1 2019

Keywords

Biocompatibility
optical < Properties
optical fibers < Glass Products
phosphate < Glass Forming Systems
Raman spectroscopy < Characterization
thermal < Properties

Disciplines

Ceramic Materials
Electrical and Computer Engineering

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10.1111/ijag.13106License: CC BY

https://doi.org/10.1111/ijag.13106

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@article{89e3813e4f064ccb97b9df123cdc83fd,

title = "Characterization of 20Na₂O·30((1−x)CaO·xSrO)·50P₂O₅ Glasses for a Resorbable Optical Fiber Application",

abstract = " Resorbable glasses with nominal molar compositions of 20Na 2 O·30[(1−x)CaO·xSrO]·50P 2 O 5 , where x = 0, 0.25, 0.50, 0.75, and 1, were prepared and characterized. With the replacement of CaO by SrO, the molar volume, refractive index, and coefficient of thermal expansion increased, and the glass transition temperature, crystallization temperature, and viscosity decreased. The replacement of CaO by SrO decreased the dissolution rate in 37°C water by nearly an order of magnitude. Resorbable glass fibers drawn from melts of the 20Na 2 O·30CaO·50P 2 O 5 glass exhibited decreasing transmission of laser light (632 nm) in a predictable way as the fiber dissolved in a phosphate buffer solution. This demonstrated that these glasses could be used to produce resorbable fibers for temporary biosensing or therapeutic applications.",

keywords = "Biocompatibility, optical < Properties, optical fibers < Glass Products, phosphate < Glass Forming Systems, Raman spectroscopy < Characterization, thermal < Properties",

author = "Freudenberger, \{Parker T.\} and Akira Saitoh and Hikaru Ikeda and Adnan, \{Md Shibab\} and Hiromichi Takebe and Shingo Nakane and Chang-Soo Kim and Brow, \{Richard K.\}",

note = "Publisher Copyright: {\textcopyright} 2019 The American Ceramic Society and Wiley Periodicals, Inc",

year = "2019",

month = jul,

day = "1",

doi = "10.1111/ijag.13106",

language = "American English",

volume = "10",

pages = "378--390",

journal = "International Journal of Applied Glass Science",

issn = "2041-1294",

number = "3",

}

TY - JOUR

T1 - Characterization of 20Na₂O·30((1−x)CaO·xSrO)·50P₂O₅ Glasses for a Resorbable Optical Fiber Application

AU - Freudenberger, Parker T.

AU - Saitoh, Akira

AU - Ikeda, Hikaru

AU - Adnan, Md Shibab

AU - Takebe, Hiromichi

AU - Nakane, Shingo

AU - Kim, Chang-Soo

AU - Brow, Richard K.

PY - 2019/7/1

Y1 - 2019/7/1

N2 - Resorbable glasses with nominal molar compositions of 20Na 2 O·30[(1−x)CaO·xSrO]·50P 2 O 5 , where x = 0, 0.25, 0.50, 0.75, and 1, were prepared and characterized. With the replacement of CaO by SrO, the molar volume, refractive index, and coefficient of thermal expansion increased, and the glass transition temperature, crystallization temperature, and viscosity decreased. The replacement of CaO by SrO decreased the dissolution rate in 37°C water by nearly an order of magnitude. Resorbable glass fibers drawn from melts of the 20Na 2 O·30CaO·50P 2 O 5 glass exhibited decreasing transmission of laser light (632 nm) in a predictable way as the fiber dissolved in a phosphate buffer solution. This demonstrated that these glasses could be used to produce resorbable fibers for temporary biosensing or therapeutic applications.

AB - Resorbable glasses with nominal molar compositions of 20Na 2 O·30[(1−x)CaO·xSrO]·50P 2 O 5 , where x = 0, 0.25, 0.50, 0.75, and 1, were prepared and characterized. With the replacement of CaO by SrO, the molar volume, refractive index, and coefficient of thermal expansion increased, and the glass transition temperature, crystallization temperature, and viscosity decreased. The replacement of CaO by SrO decreased the dissolution rate in 37°C water by nearly an order of magnitude. Resorbable glass fibers drawn from melts of the 20Na 2 O·30CaO·50P 2 O 5 glass exhibited decreasing transmission of laser light (632 nm) in a predictable way as the fiber dissolved in a phosphate buffer solution. This demonstrated that these glasses could be used to produce resorbable fibers for temporary biosensing or therapeutic applications.

KW - Biocompatibility

KW - optical < Properties

KW - optical fibers < Glass Products

KW - phosphate < Glass Forming Systems

KW - Raman spectroscopy < Characterization

KW - thermal < Properties

UR - https://scholarsmine.mst.edu/ele_comeng_facwork/3832

UR - https://doi.org/10.1111/ijag.13106

U2 - 10.1111/ijag.13106

DO - 10.1111/ijag.13106

M3 - Article

SN - 2041-1294

VL - 10

SP - 378

EP - 390

JO - International Journal of Applied Glass Science

JF - International Journal of Applied Glass Science

IS - 3

ER -

Characterization of 20Na₂O·30((1−x)CaO·xSrO)·50P₂O₅ Glasses for a Resorbable Optical Fiber Application

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