An Unusual Open-Framework Cobalt(II) Phosphate with a Channel Structure that Exhibits Structural and Magnetic Transitions

Amitava Choudhury; Sharma Neeraj; Srinivasan R. Natarajan; Chintamani Nagesa Ramachandra Rao

doi:10.1002/1521-3773(20000901)39:17<3091::AID-ANIE3091>3.0.CO;2-6

An Unusual Open-Framework Cobalt(II) Phosphate with a Channel Structure that Exhibits Structural and Magnetic Transitions

Amitava Choudhury
, Sharma Neeraj
, Srinivasan R. Natarajan
, Chintamani Nagesa Ramachandra Rao

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Magnetic and structural transitions at low temperatures are exhibited by the novel open-framework cobalt(n) phosphate of the composition [enH ₂ ][Co _3.5 (PO ₄ ) ₃ ] (en=ethy) lenediamine), the structure of which contains 12-membered channels. In the presence of a magnetic field, the compound undergoes a. transition between two ferrimagnetic states.

Original language	American English
Journal	Angewandte Chemie International Edition
Volume	39
DOIs	https://doi.org/10.1002/1521-3773(20000901)39:17<3091::AID-ANIE3091>3.0.CO;2-6
State	Published - Sep 1 2000

Keywords

Chemical Bond
Chemical Structure
Cobalt
Cobalt Complex
Conformational Transition
Magnetic Properties
Magnetism
Phosphate, Article
Solid-State Structures
Structure Analysis
Synthesis
Temperature

Disciplines

Chemistry

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10.1002/1521-3773(20000901)39:17<3091::AID-ANIE3091>3.0.CO;2-6License: Unspecified

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title = "An Unusual Open-Framework Cobalt(II) Phosphate with a Channel Structure that Exhibits Structural and Magnetic Transitions",

abstract = " Magnetic and structural transitions at low temperatures are exhibited by the novel open-framework cobalt(n) phosphate of the composition [enH 2 ][Co 3.5 (PO 4 ) 3 ] (en=ethy) lenediamine), the structure of which contains 12-membered channels. In the presence of a magnetic field, the compound undergoes a. transition between two ferrimagnetic states.",

keywords = "Chemical Bond, Chemical Structure, Cobalt, Cobalt Complex, Conformational Transition, Magnetic Properties, Magnetism, Phosphate, Article, Solid-State Structures, Structure Analysis, Synthesis, Temperature",

author = "Amitava Choudhury and Sharma Neeraj and Natarajan, \{Srinivasan R.\} and Rao, \{Chintamani Nagesa Ramachandra\}",

year = "2000",

month = sep,

day = "1",

doi = "10.1002/1521-3773(20000901)39:17<3091::AID-ANIE3091>3.0.CO;2-6",

language = "American English",

volume = "39",

journal = "Angewandte Chemie International Edition",

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TY - JOUR

T1 - An Unusual Open-Framework Cobalt(II) Phosphate with a Channel Structure that Exhibits Structural and Magnetic Transitions

AU - Choudhury, Amitava

AU - Neeraj, Sharma

AU - Natarajan, Srinivasan R.

AU - Rao, Chintamani Nagesa Ramachandra

PY - 2000/9/1

Y1 - 2000/9/1

N2 - Magnetic and structural transitions at low temperatures are exhibited by the novel open-framework cobalt(n) phosphate of the composition [enH 2 ][Co 3.5 (PO 4 ) 3 ] (en=ethy) lenediamine), the structure of which contains 12-membered channels. In the presence of a magnetic field, the compound undergoes a. transition between two ferrimagnetic states.

AB - Magnetic and structural transitions at low temperatures are exhibited by the novel open-framework cobalt(n) phosphate of the composition [enH 2 ][Co 3.5 (PO 4 ) 3 ] (en=ethy) lenediamine), the structure of which contains 12-membered channels. In the presence of a magnetic field, the compound undergoes a. transition between two ferrimagnetic states.

KW - Chemical Bond

KW - Chemical Structure

KW - Cobalt

KW - Cobalt Complex

KW - Conformational Transition

KW - Magnetic Properties

KW - Magnetism

KW - Phosphate, Article

KW - Solid-State Structures

KW - Structure Analysis

KW - Synthesis

KW - Temperature

UR - https://scholarsmine.mst.edu/chem_facwork/1783

UR - https://doi.org/10.1002/1521-3773(20000901)39:17<3091::AID-ANIE3091>3.0.CO;2-6

U2 - 10.1002/1521-3773(20000901)39:17<3091::AID-ANIE3091>3.0.CO;2-6

DO - 10.1002/1521-3773(20000901)39:17<3091::AID-ANIE3091>3.0.CO;2-6

M3 - Article

SN - 1521-3773

VL - 39

JO - Angewandte Chemie International Edition

JF - Angewandte Chemie International Edition

ER -

An Unusual Open-Framework Cobalt(II) Phosphate with a Channel Structure that Exhibits Structural and Magnetic Transitions

Abstract

Keywords

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