An Organically Templated Open-Framework Cadmium Selenite

Intyaj Pasha; Amitava Choudhury; Chintamani Nagesa Ramachandra Rao

doi:10.1016/S1293-2558(02)00100-0

An Organically Templated Open-Framework Cadmium Selenite

Intyaj Pasha
, Amitava Choudhury
, Chintamani Nagesa Ramachandra Rao

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

An open-framework cadmium selenite of the composition [CdCl ₂ (HSeO ₃ ) ₂ ](enH ₂ ) has been obtained by a solution-mediated reaction. This compound crystallizes in a monoclinic unit cell with the space group P2 ₁ / c (No. 14) and the lattice parameters a = 8.2888 (7) Å, b = 7.8071(7) Å, c = 9.9430(8) Å, β = 112.444(2)°, V = 594.69(9), Z = 4. The selenite has a layered structure containing macroanionic sheets of [CdCl ₂ (HSeO ₃ ) ₂ ] ^2- , with the protonated ethylenediamine (en) molecules in the interlamellar space. This cadmium selenite is the first few members of the new family of open-framework metal selenites.

Original language	American English
Journal	Solid State Sciences
Volume	5
DOIs	https://doi.org/10.1016/S1293-2558(02)00100-0
State	Published - Jan 1 2003

Keywords

Article
Cadmium Chloride
Cadmium Derivative
Cadmium Selenite
Calcium Compounds
Chemical Analysis
Chemical Reaction
Chemical Structure
Composition
Crystal Structure
Crystallization
Lattice Constants
Molecule
Negative Ions
Proton Transport
Selenite
Selenium Derivative
Unclassified Drug
Unit Cells

Disciplines

Chemistry

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https://doi.org/10.1016/S1293-2558(02)00100-0

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@article{cc9906ea01594fd49bbb457afcd3759a,

title = "An Organically Templated Open-Framework Cadmium Selenite",

abstract = " An open-framework cadmium selenite of the composition [CdCl 2 (HSeO 3 ) 2 ](enH 2 ) has been obtained by a solution-mediated reaction. This compound crystallizes in a monoclinic unit cell with the space group P2 1 / c (No. 14) and the lattice parameters a = 8.2888 (7) {\AA}, b = 7.8071(7) {\AA}, c = 9.9430(8) {\AA}, β = 112.444(2)°, V = 594.69(9), Z = 4. The selenite has a layered structure containing macroanionic sheets of [CdCl 2 (HSeO 3 ) 2 ] 2- , with the protonated ethylenediamine (en) molecules in the interlamellar space. This cadmium selenite is the first few members of the new family of open-framework metal selenites.",

keywords = "Article, Cadmium Chloride, Cadmium Derivative, Cadmium Selenite, Calcium Compounds, Chemical Analysis, Chemical Reaction, Chemical Structure, Composition, Crystal Structure, Crystallization, Lattice Constants, Molecule, Negative Ions, Proton Transport, Selenite, Selenium Derivative, Unclassified Drug, Unit Cells",

author = "Intyaj Pasha and Amitava Choudhury and Rao, \{Chintamani Nagesa Ramachandra\}",

year = "2003",

month = jan,

day = "1",

doi = "10.1016/S1293-2558(02)00100-0",

language = "American English",

volume = "5",

journal = "Solid State Sciences",

}

TY - JOUR

T1 - An Organically Templated Open-Framework Cadmium Selenite

AU - Pasha, Intyaj

AU - Choudhury, Amitava

AU - Rao, Chintamani Nagesa Ramachandra

PY - 2003/1/1

Y1 - 2003/1/1

N2 - An open-framework cadmium selenite of the composition [CdCl 2 (HSeO 3 ) 2 ](enH 2 ) has been obtained by a solution-mediated reaction. This compound crystallizes in a monoclinic unit cell with the space group P2 1 / c (No. 14) and the lattice parameters a = 8.2888 (7) Å, b = 7.8071(7) Å, c = 9.9430(8) Å, β = 112.444(2)°, V = 594.69(9), Z = 4. The selenite has a layered structure containing macroanionic sheets of [CdCl 2 (HSeO 3 ) 2 ] 2- , with the protonated ethylenediamine (en) molecules in the interlamellar space. This cadmium selenite is the first few members of the new family of open-framework metal selenites.

AB - An open-framework cadmium selenite of the composition [CdCl 2 (HSeO 3 ) 2 ](enH 2 ) has been obtained by a solution-mediated reaction. This compound crystallizes in a monoclinic unit cell with the space group P2 1 / c (No. 14) and the lattice parameters a = 8.2888 (7) Å, b = 7.8071(7) Å, c = 9.9430(8) Å, β = 112.444(2)°, V = 594.69(9), Z = 4. The selenite has a layered structure containing macroanionic sheets of [CdCl 2 (HSeO 3 ) 2 ] 2- , with the protonated ethylenediamine (en) molecules in the interlamellar space. This cadmium selenite is the first few members of the new family of open-framework metal selenites.

KW - Article

KW - Cadmium Chloride

KW - Cadmium Derivative

KW - Cadmium Selenite

KW - Calcium Compounds

KW - Chemical Analysis

KW - Chemical Reaction

KW - Chemical Structure

KW - Composition

KW - Crystal Structure

KW - Crystallization

KW - Lattice Constants

KW - Molecule

KW - Negative Ions

KW - Proton Transport

KW - Selenite

KW - Selenium Derivative

KW - Unclassified Drug

KW - Unit Cells

UR - https://scholarsmine.mst.edu/chem_facwork/1882

UR - https://doi.org/10.1016/S1293-2558(02)00100-0

U2 - 10.1016/S1293-2558(02)00100-0

DO - 10.1016/S1293-2558(02)00100-0

M3 - Article

VL - 5

JO - Solid State Sciences

JF - Solid State Sciences

ER -

An Organically Templated Open-Framework Cadmium Selenite

Abstract

Keywords

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