Ab Initio Structural Studies of Cyclobutylmethyl Cations: Effect of Fluoroalkyl Groups on the Relative Stability of the Carbocations

Ab initio calculations at MP2/cc-pVTZ level show that the trifluoromethyl group has a strong destabilizing effect on the nonclassical, σ-bridged cyclobutylmethyl cations. The GIAO-MP2 derived ¹³ C NMR chemical shifts indicate substantial charge delocalization from the neighboring cyclobutyl ring for carbocations with an α-fluorolkyl group as compared to the 1-cyclobutylethyl cation, and this enhanced charge delocalization in case of the α-(trifluoromethyl)cyclobutylmethyl cation would lead to the ring-opening rearrangement to form the relatively more stable nonclassical primary cyclobutylmethyl cation, in which the carbocation center is farthest from the strongly electron-withdrawing trifluoromethyl group.