A “Star” Antiferromagnet: A Polymeric Iron(III) Acetate That Exhibits Both Spin Frustration and Long-Range Magnetic Ordering

Yanzhen Zheng; Mingliang Tong; Wei Xue; Weixiong Zhang; Xiaoming Chen; Fernande Grandjean; Gary J. Long

doi:10.1002/anie.200701954

A “Star” Antiferromagnet: A Polymeric Iron(III) Acetate That Exhibits Both Spin Frustration and Long-Range Magnetic Ordering

Yanzhen Zheng
, Mingliang Tong
, Wei Xue
, Weixiong Zhang
, Xiaoming Chen
, Fernande Grandjean
, Gary J. Long

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Star formation: Polymeric [Fe ₃ (µ ₃ -O)(µ-OAc) ₆ (H ₂ O) ₃ ][Fe ₃ (µ ₃ -O)µ-OAc) _7.5 ₂ ·7H ₂ O is synthesized by linking triangular {Fe ₃ (µ ₃ -O)} clusters through anti-anti bridging acetate ligands. Spin frustration and long-range magnetic order coexist in this compound below 4.5 K

Original language	American English
Journal	Angewandte Chemie International Edition
Volume	46
DOIs	https://doi.org/10.1002/anie.200701954
State	Published - Jul 1 2007

Keywords

Acetate Ligands
Spin Frustration
Antiferromagnetic Materials
Magnetic Properties
Magnetization
Materials Science
Mössbauer Spectroscopy
Spin Dynamics
Iron Compounds
Ferric Acetate
Ferric Ion
Polymer
Unclassified Drug
Chemical Structure
Chemistry
Magnetism
Ferric Compounds
Magnetics
Molecular Structure
Polymers
Spectroscopy
Mössbauer

Disciplines

Chemistry

Access to Document

10.1002/anie.200701954License: CC BY

https://doi.org/10.1002/anie.200701954

Cite this

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title = "A “Star” Antiferromagnet: A Polymeric Iron(III) Acetate That Exhibits Both Spin Frustration and Long-Range Magnetic Ordering",

abstract = " Star formation: Polymeric [Fe 3 (µ 3 -O)(µ-OAc) 6 (H 2 O) 3 ][Fe 3 (µ 3 -O)µ-OAc) 7.5 2 ·7H 2 O is synthesized by linking triangular \{Fe 3 (µ 3 -O)\} clusters through anti-anti bridging acetate ligands. Spin frustration and long-range magnetic order coexist in this compound below 4.5 K",

keywords = "Acetate Ligands, Spin Frustration, Antiferromagnetic Materials, Magnetic Properties, Magnetization, Materials Science, M{\"o}ssbauer Spectroscopy, Spin Dynamics, Iron Compounds, Ferric Acetate, Ferric Ion, Polymer, Unclassified Drug, Chemical Structure, Chemistry, Magnetism, Ferric Compounds, Magnetics, Molecular Structure, Polymers, Spectroscopy, M{\"o}ssbauer",

author = "Yanzhen Zheng and Mingliang Tong and Wei Xue and Weixiong Zhang and Xiaoming Chen and Fernande Grandjean and Long, \{Gary J.\}",

year = "2007",

month = jul,

day = "1",

doi = "10.1002/anie.200701954",

language = "American English",

volume = "46",

journal = "Angewandte Chemie International Edition",

issn = "1521-3773",

}

TY - JOUR

T1 - A “Star” Antiferromagnet: A Polymeric Iron(III) Acetate That Exhibits Both Spin Frustration and Long-Range Magnetic Ordering

AU - Zheng, Yanzhen

AU - Tong, Mingliang

AU - Xue, Wei

AU - Zhang, Weixiong

AU - Chen, Xiaoming

AU - Grandjean, Fernande

AU - Long, Gary J.

PY - 2007/7/1

Y1 - 2007/7/1

N2 - Star formation: Polymeric [Fe 3 (µ 3 -O)(µ-OAc) 6 (H 2 O) 3 ][Fe 3 (µ 3 -O)µ-OAc) 7.5 2 ·7H 2 O is synthesized by linking triangular {Fe 3 (µ 3 -O)} clusters through anti-anti bridging acetate ligands. Spin frustration and long-range magnetic order coexist in this compound below 4.5 K

AB - Star formation: Polymeric [Fe 3 (µ 3 -O)(µ-OAc) 6 (H 2 O) 3 ][Fe 3 (µ 3 -O)µ-OAc) 7.5 2 ·7H 2 O is synthesized by linking triangular {Fe 3 (µ 3 -O)} clusters through anti-anti bridging acetate ligands. Spin frustration and long-range magnetic order coexist in this compound below 4.5 K

KW - Acetate Ligands

KW - Spin Frustration

KW - Antiferromagnetic Materials

KW - Magnetic Properties

KW - Magnetization

KW - Materials Science

KW - Mössbauer Spectroscopy

KW - Spin Dynamics

KW - Iron Compounds

KW - Ferric Acetate

KW - Ferric Ion

KW - Polymer

KW - Unclassified Drug

KW - Chemical Structure

KW - Chemistry

KW - Magnetism

KW - Ferric Compounds

KW - Magnetics

KW - Molecular Structure

KW - Polymers

KW - Spectroscopy

KW - Mössbauer

UR - https://scholarsmine.mst.edu/chem_facwork/111

UR - https://doi.org/10.1002/anie.200701954

U2 - 10.1002/anie.200701954

DO - 10.1002/anie.200701954

M3 - Article

C2 - 17615608

SN - 1521-3773

VL - 46

JO - Angewandte Chemie International Edition

JF - Angewandte Chemie International Edition

ER -

A “Star” Antiferromagnet: A Polymeric Iron(III) Acetate That Exhibits Both Spin Frustration and Long-Range Magnetic Ordering

Abstract

Keywords

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