A Hexanuclear Copper Arylselenolate: Synthesis, Structure and Proposal for Its Rearrangement

Dietmar Ohlmann; Hans Pritzkow; Hansjorg Grutzmacher; Mitchell Anthamatten; Rainer Glaser

doi:10.1039/C39950001011

A Hexanuclear Copper Arylselenolate: Synthesis, Structure and Proposal for Its Rearrangement

Dietmar Ohlmann
, Hans Pritzkow
, Hansjorg Grutzmacher
, Mitchell Anthamatten
, Rainer Glaser

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Copper(I) oxide reacts with selenol 2,4,6-Pr ⁱ ₃ C ₆ H ₂ -SeH in ethanol to give the hexanuclear copper(I) selenolate {Cu[Se(2,4,6-Pr ⁱ ₃ C ₆ H ₂ )]}6 of 6 , the solid state structure of which consists of a disordered Cu ₆ octahedron embedded in an antiprism formed by six selenium centres of the selenolate residues; this leads us to propose an exchange mechanism for the equilibration of all copper positions.

Original language	American English
Journal	Journal of the Chemical Society, Chemical Communications
DOIs	https://doi.org/10.1039/C39950001011
State	Published - Jan 1 1995

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Chemistry

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title = "A Hexanuclear Copper Arylselenolate: Synthesis, Structure and Proposal for Its Rearrangement",

abstract = " Copper(I) oxide reacts with selenol 2,4,6-Pr i 3 C 6 H 2 -SeH in ethanol to give the hexanuclear copper(I) selenolate \{Cu[Se(2,4,6-Pr i 3 C 6 H 2 )]\}6 of 6 , the solid state structure of which consists of a disordered Cu 6 octahedron embedded in an antiprism formed by six selenium centres of the selenolate residues; this leads us to propose an exchange mechanism for the equilibration of all copper positions.",

author = "Dietmar Ohlmann and Hans Pritzkow and Hansjorg Grutzmacher and Mitchell Anthamatten and Rainer Glaser",

year = "1995",

month = jan,

day = "1",

doi = "10.1039/C39950001011",

language = "American English",

journal = "Journal of the Chemical Society, Chemical Communications",

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TY - JOUR

T1 - A Hexanuclear Copper Arylselenolate: Synthesis, Structure and Proposal for Its Rearrangement

AU - Ohlmann, Dietmar

AU - Pritzkow, Hans

AU - Grutzmacher, Hansjorg

AU - Anthamatten, Mitchell

AU - Glaser, Rainer

PY - 1995/1/1

Y1 - 1995/1/1

N2 - Copper(I) oxide reacts with selenol 2,4,6-Pr i 3 C 6 H 2 -SeH in ethanol to give the hexanuclear copper(I) selenolate {Cu[Se(2,4,6-Pr i 3 C 6 H 2 )]}6 of 6 , the solid state structure of which consists of a disordered Cu 6 octahedron embedded in an antiprism formed by six selenium centres of the selenolate residues; this leads us to propose an exchange mechanism for the equilibration of all copper positions.

AB - Copper(I) oxide reacts with selenol 2,4,6-Pr i 3 C 6 H 2 -SeH in ethanol to give the hexanuclear copper(I) selenolate {Cu[Se(2,4,6-Pr i 3 C 6 H 2 )]}6 of 6 , the solid state structure of which consists of a disordered Cu 6 octahedron embedded in an antiprism formed by six selenium centres of the selenolate residues; this leads us to propose an exchange mechanism for the equilibration of all copper positions.

UR - https://scholarsmine.mst.edu/chem_facwork/2725

UR - http://doi.org/10.1039/C39950001011

U2 - 10.1039/C39950001011

DO - 10.1039/C39950001011

M3 - Article

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

ER -

A Hexanuclear Copper Arylselenolate: Synthesis, Structure and Proposal for Its Rearrangement

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